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爱游戏ayx官网首页成为巴塞罗那亚洲区官方合作伙伴
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改性树脂基体/玻璃纤维界面粘结性能演化与分子动力学模拟

Evolution of interfacial bonding performance and molecular dynamics simulation of modified resin matrix/glass fiber interface

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    摘要

  • 摘要: 玻璃纤维与环氧树脂界面的粘结性能直接影响玻璃纤维增强复合材料(GFRP)内部的应力传递和耐久性。通过纳米材料杂化与硅氧烷活性低聚物协同增效,制备界面粘结性能及耐蚀性能优异的改性环氧树脂基体。采用单丝拉拔试验与数字显微镜相结合技术研究了改性树脂/纤维界面粘结性能演变规律,并通过分子动力学模拟从原子角度探究碱性环境对界面粘结性能的影响。结果表明:相较未改性环氧树脂,改性树脂/纤维的界面粘结力提升了约33.3%,界面处最大应变增加了约53.84%,腐蚀30天后界面粘结力提高了约130.7%。分子动力学模拟表明,改性树脂基体增强了Oepoxy-Hs的键合作用,延迟界面键合破坏,减缓腐蚀环境下界面处环氧树脂相对浓度及氢键的下降幅值,增强界面粘结性能。

     

    Abstract: The interfacial bonding performance between glass fiber and epoxy resin directly affects the stress transfer and durability of glass fiber reinforced polymer (GFRP) composites. By hybridizing nanomaterials and synergistically enhancing with siloxane-active oligomers, a modified epoxy resin matrix with superior interfacial bonding and corrosion resistance properties was developed. The evolution of the interfacial bonding performance between the modified resin and fiber was investigated using single-filament tensile tests and digital image correlation microscopy. The underlying mechanism of interfacial degradation in an alkaline environment was elucidated through molecular dynamics simulations from an atomic perspective. The results indicate that, compared to the unmodified system, the modified resin/fiber interface exhibits an approximately 33.3% increase in interfacial bonding strength and an approximately 53.84% increase in maximum interfacial strain. After 30 days of corrosion, the interfacial bonding strength of the modified system shows an approximately 130.7% improvement relative to the corroded unmodified system. Molecular dynamics simulations reveal that the modified resin matrix strengthens the Oepoxy-Hs bonding interaction, delays interfacial bond failure, mitigates the reduction in both epoxy resin concentration and hydrogen bond density at the interface under corrosive conditions, and improves interfacial adhesion properties.

     

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    参考文献(29)

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